Steam-based thermal technologies are widely used in the development of heavy and extra-heavy oil reservoirs. Particular attention is paid to improving the efficiency of thermal energy utilization injected into the reservoir, including through the implementation of in-situ upgrading processes. The use of transition metal-based catalysts contributes to a reduction in oil viscosity and an increase in its mobility. This leads to an increase in oil recovery. A promising approach is the application of reagents capable of disrupting the supramolecular structures of asphaltenes. This enhances the accessibility of weak carbon–heteroatom bonds and promotes their subsequent degradation under hydrothermal conditions. This study investigates the effect of a thermally stable surfactant-peptizer on the physicochemical properties of heavy oil from the Aksenovskoye field under pilot field conditions. Oil samples were collected over a four-week period, four months after reagent injection. Rheological properties, group composition (SARA), and various characteristics of asphaltenes were analyzed. To elucidate the nature of intermolecular interactions in asphaltene structures, quantum chemical calculations were performed, including Hirshfeld surface analysis, which enabled to identify potential interaction sites and explain the tendency of asphaltenes to aggregate. The obtained results confirm that the action of the surfactant-peptizer (TU 20.59.59-003-02066730-2025) leads to the dispersion of asphaltene aggregates, increased oil mobility under reservoir conditions, and enhanced oil recovery.
References
1. Ganeeva Yu.M., Yusupova T.N., Romanov G.V., Asphaltene nano-aggregates: structure, phase transitions and effect on petroleum systems (In Russ.), Uspekhi
khimii = Russian Chemical Reviews, 2011, V. 80, no. 10, pp. 1034–10502. Fedorov R.A., Akopyan A.V., Anisimov A.V., Karakhanov E.A., Peroxide oxidative desulfurization of crude petroleum in the presence of fatty acids, International Journal of Biology and Chemistry, 2018, V. 11, No. 2, pp. 173–178, DOI: https://doi.org/10.26577/ijbch-2018-2-337
3. Kholmurodov T., Vakhin A.V., Mirzaev O. et al., Non-ionic surfactant influence on peptization of asphaltene agglomerates in heavy oil under hydrothermal conditions in the Na-Fe3O4 catalyst presence, Fuel, 2025, V. 393, pp. 134966, DOI: https://doi.org/10.1016/j.fuel.2025.134966
4. Kholmurodov T.A., Mirzaev O.O., Vakhin A.V. et al., The phenomenon of asphaltenes’ peptization to improve steam-thermal methods efficiency for heavy oil fields development (In Russ.), Neftyanoe khozyaystvo = Oil Industry, 2024, No. 7, pp. 109–112, DOI: https://doi.org/10.24887/0028-2448-2024-7-109-112
5. Kholmurodov T., Tajik A., Galyametdinov Y. et al., Mechanism of surfactant peptization in the process hydrocatalytic degradation of asphaltenes in heavy oils, Fuel, 2025, V. 381, DOI: https://doi.org/10.1016/j.fuel.2024.133490
6. Malaniy S.Ya., Slavkina O.V., Ryazanov A.A. et al., Field test of catalytic aquathermolysis technology at Strelovskoye oil field in the Samara region (In Russ.), Neftyanoe khozyaystvo = Oil Industry, 2022, no. 12, pp. 118–121, DOI: http://doi.org/10.24887/0028-2448-2022-12-118-121
7. Protsenko A.N., Malaniy S.Ya., Bakumenko E.A. et al., Downhole catalytic hydrogenation of carbon dioxide during thermal enhanced heavy oil recovery (In Russ.), Neftyanoe khozyaystvo = Oil Industry, 2022, no. 12, pp. 114-117, DOI: https://doi.org/10.24887/0028-2448-2022-12-114-117
8. Patent RU2794400C1. Composition for intensifying the production of hard-to-recover hydrocarbon reserves and a method for its production, Inventors: Kholmurodov T.A., Vakhin A.V., Sitnov S.A., Mirzaev O.O.
9. Betiha M.A., Elmetwally A.E., Al-Sabagh A.M., Mahmoud T., Catalytic aquathermolysis for altering the rheology of asphaltic crude oil using ionic liquid modified magnetic MWCNT, Energy and Fuels, 2020, V. 34(9), pp. 11353–11364, DOI: https://doi.org/10.1021/acs.energyfuels.0c02062
10. Vakhin A.V., Aliev F.A., Mukhamatdinov I.I. et al., Extra-heavy oil aquathermolysis using nickel-based catalyst: Some aspects of in-situ transformation of catalyst precursor, Catalysts, 2021, V. 11(2), No. 189, pp. 1–22, DOI: https://doi.org/10.3390/catal11020189
11. Kholmurodov T.A., Aliev F.A., Mirzaev O.O. et al., Hydrothermal in-reservoir upgrading of heavy oil in the presence of non-ionic surfactants, Processes, 2022, V. 10, No. 11, DOI: https://doi.org/10.3390/pr10112176
12. Kholmurodov T.A., Mirzaev O.O., Affane B. et al., Thermochemical upgrading of heavy crude oil in reservoir conditions, Processes, 2023, V. 11, No. 7,
DOI: https://doi.org/10.3390/pr11072156
13. Yanping Wang a , Qiuxia Wang b, Da Yang et al., Synthesis and properties evaluation of novel Gemini surfactant with temperature tolerance and salt resistance for heavy oil, Journal of Molecular Liquids, 2023, V. 382, DOI: https://doi.org/10.1016/j.molliq.2023.121851
14. Okhotnikova E.S., Barskaya E.E., Ganeeva Y.M. et al., Catalytic conversion of oil in model and natural reservoir rocks, Processes, 2023, V. 11, No. 8,
DOI: https://doi.org/10.3390/pr11082380
15. Aliev F., Mirzayev O., Kholmurodov T. et al., Experimental insights into catalytic conversion of carbon dioxide during in-reservoir hydrothermal upgrading of heavy oil, Fuel, 2025, V. 396, DOI: https://doi.org/10.1016/j.fuel.2025.135326