Investigation of the effectiveness of an acoustic shelf-type degasser for removing hydrogen sulfide from crude oil during treatment

UDK: 665.62
DOI: 10.24887/0028-2448-2026-7-134-138
Key words: acoustic treatment, hydrogen sulfide, shelf-type degasser, degassing, hydrogen sulfide separation
Authors: A.V. Dengaev (Gubkin University, RF, Moscow); V.E. Katnov (Kazan (Volga Region) Federal University, RF, Kazan); R.G. Nurgaliev (RITEK LLC, RF, Volgograd); A.P. Paliy (RITEK LLC, RF, Volgograd); D.A. Volkov (LUKOIL-Engineering LLC, RF, Moscow); A.N. Korol (LUKOIL-Engineering LLC, RF, Moscow); S.A. Trubitsina (Kazan (Volga Region) Federal University, RF, Kazan); A.A. Kayumov (Kazan (Volga Region) Federal University, RF, Kazan); A.F. Maksimenko (Gubkin University, RF, Moscow); A.V. Vakhin (Kazan (Volga Region) Federal University, RF, Kazan)

One of the typical challenges in the development of mature fields is the progressive water cut increase in the production, accompanied by a higher concentration of associated gases, particularly highly toxic and corrosion-active hydrogen sulfide H2S. The presence of dissolved H2S in marketable crude oil creates significant technological, economic, and environmental risks. Due to increasingly stringent quality standards and feedstock transportation requirements, the allowable H2S concentration in crude oil is regulated and must not exceed 20 ppm. Existing degassing methods are often energy-intensive, costly, or insufficiently effective in achieving the target specifications. This creates a need to upgrade the process equipment of oil treatment facilities and to develop new technical solutions. This paper considers a fundamentally new degassing unit for hydrogen-sulfide-containing crude oil based on shelf-type acoustic emitters, which promote the removal of sulfur-containing gas from the bulk oil phase through the action of physical cavitation fields. The main objective of the work was pilot-scale field testing of the developed cavitation-based oil treatment technology for the selective removal of hydrogen sulfide. The studies were carried out directly at an oil production facility of TatRITEKneft Territorial Production Enterprise. The tests confirmed the effectiveness of the technology under actual field operating conditions and demonstrated a high level of crude oil purification from hydrogen sulfide. The use of a physical treatment method, as opposed to chemical scavengers, reduces operating costs and improves the environmental safety of the process.

References

1. Sakhabutdinov R.Z., Shatalov A.N., Garifullin R.M. et al., Podgotovka i ochistka neftey ot serovodoroda (Preparation and purification of oils from hydrogen sulfide), Kazan: Ikhlas Publ., 2012, 162 p.

2. Mazgarov A.M., Kornetova O.M., Tekhnologii ochistki poputnogo neftyanogo gaza ot serovodoroda (Technologies for associated petroleum gas desulphurization) Kazan’: Publ. of KFU, 2015, 70 p.

3. Khuramshin R.T., Ismagilov F.R., Vishnevskaya E.E. et al., On the need to switch to a new type of sinks of hydrogen sulphide and mercaptans in oil, oil products, and gas (In Russ.), Mir nefteproduktov, 2018, No. 3, pp. 4–10.

4. Vetrova T.K., Morozov V.A., Dorogochinskaya V.A. et al., Effectiveness of various types of absorbers of hydrogen sulfide in residual fuel oil (In Russ.), Khimiya i tekhnologiya topliv i masel, 2011, No. 6, pp. 25–26.

5. Anufriev A.A., Sovershenstvovanie fizicheskikh metodov ochistki nefti ot serovodoroda (Improving physical methods for removing hydrogen sulfide from oil): thesis of candidate of technical science, Bugul’ma, 2023.

6. Shipilov D.D., Sovershenstvovanie tekhnologiy ochistki nefti ot serovodoroda na promyslovykh ob»ektakh (Improving technologies for oil purification from hydrogen sulfide at oilfield facilities): thesis of candidate of technical science, Bugul’ma, 2011.

7. Nikitin A.A., Karasev E.N., Dutlov E.V. et al., Selection of optimum technologyof decrease of hydrogen sulfidein petroleum residue (In Russ.), Neftepererabotka i neftekhimiya, 2014, No. 9, pp. 19–23.

8. Sakhabutdinov R.Z., Anufriev A.A., Shatalov A.N., Shipilov D.D., Improvement of hydrogen sulfide stripping physical methods (In Russ.), Ekspozitsiya Neft’ Gaz, 2017, no. 3, pp. 39–41.

9. Mullakaev M.S., Ul’trazvukovaya intensifikatsiya tekhnologicheskikh protsessov dobychi i pererabotki nefti, ochistki neftezagryaznennykh vod i gruntov (Ultrasonic intensification of technological processes of oil production and refining, purification of oil-contaminated waters and soils): thesis of candidate of technical science, Moscow, 2011.

10. Suleymanov M.A., Verbitskiy V.S., Evaluation of the application of the acoustic degassing method in oil production wells (In Russ.), Delovoy zhurnal Neftegaz.RU, 2024, No. 11(155), pp. 40–45.

11. Alfayaad A.G.Kh., Kemalov R.A., Kemalov A.F., Valiev D.Z., WaveWellTech: innovatsionnaya volnovaya tekhnologiya dlya intensifikatsii dobychi nefti (WaveWellTech: Innovative wave technology for enhanced oil production), Kazan’: Publ. of Kazan University, 2024, 123 p.

12. Alan-Reys N.V., Es’kin A.A., Zhilyakova T.S., Unru P.P., Effect of ultrasonic radiation on the air bubbles ascent time (In Russ.), Vestnik Inzhenernoy shkoly Dal’nevostochnogo federal’nogo universiteta, 2020, No. 2(43), pp. 116–123, DOI: https://doi.org/10.24866/2227-6858/2020-2-12

13. Tronov V.P., Separatsiya gaza i sokrashchenie poter’ nefti (Gas separation and reduction of oil losses), Kazan’: FEN Publ., 2002, 407 p.

14. Skoblo A. I., Molokanov Yu.K., Shchelkunov A.I., Protsessy i apparaty neftegazopererabotki i neftekhimii (Processes and equipment for oil and gas refining and petrochemistry), Moscow: Nedra Publ., 2000, 677 p.

15. Promtov M.A., Pul’satsionnye apparaty rotornogo tipa: teoriya i praktika: monografiya (Rotary-type pulsation devices: theory and practice: monograph), Moscow: Mashinostroenie-1 Publ., 2001, 260 p.



Attention!
To buy the complete text of article (Russian version a format - PDF) or to read the material which is in open access only the authorized visitors of the website can. .