Directions for the development of geopolymer materials technologies for the production of grouting solutions and the disposal of industrial waste

UDK: 691.544:622.276
DOI: 10.24887/0028-2448-2024-9-127-131
Key words: cement, compressive strength, geopolymer, fly ash, blast-furnace slag
Authors: R.R. Romanov (Gazprom Neft Companу Group, RF, Saint Petersburg; ITMO University, RF, Saint Petersburg) T.N. Nosenko (ITMO University, RF, Saint Petersburg)

Currently, most of the fields with easily accessible oil are depleted. The development of hard-to-recover reserves is fraught with difficulties, which requires careful preparation and study during the preliminary stages, one of which is the process of cementing and fixing wells. Improper selection of the components has negative consequences, among which are griffin formation, groundwater circulation and gas breakthroughs. Investigation on the search for alternative materials for the preparation of grouting solutions is also aimed at reducing the impact on ecology and environment. The use of geopolymers can be considered as one of the most promising technologies for the construction and anchoring of wells. The material received its official name in 1970 due to the works of French chemist-scientist Joseph Davidovich, according to which the composition is based on an aluminosilicate binder and an alkaline activator. The use of inorganic waste from industrial enterprises of the fuel and metallurgical industries is proposed as a base material. Such materials, when interacting with aqueous solutions of alkali metals, are able to form a strong and durable structure that is comparable or superior to similar Portland cement-based samples. The characteristics of clinker-based cement are conditioned by «natural» properties, which depend on the firing temperature, quality of raw materials, fineness of grinding and a number of other factors. The use of geopolymer composition can provide not only increased economic efficiency of the resulting product, but also environmental safety in combination with increased resistance to thermobaric conditions of the formation.

References

1. Nikolaev K., Return to Achimovka. Comparative characteristics of Achimov and Neocomian formations in the Noyabrsk region (In Russ.), ROGTEC Rossiyskie neftegazovye tekhnologii, 2015, V. 42, pp. 16–22.

2. Zvarygin V.I., Tamponazhnye smesi (Cementing mixtures), Krasnoyarsk: Publ. of Siberian Federal Universitym, 2014, 216 p.

3. Gomes K.C., Carvalho M., de Paula Diniz D. et al., Carbon emissions associated with two types of foundations: CP-II Portland cement-based composite vs. geopolymer concrete, Matéria (Rio de Janeiro), 2019, V. 24(4), DOI: http://doi.org/10.1590/s1517-707620190004.0850

4. Vairagade V.S., Kedar A.P., Patel R., Supplementary cementitious materials for green concrete, Journal of Advanced Research in Construction & Urban Architecture, 2017, V. 2(1&2), pp. 25–30.

5. Eroshkina N.A., Korovkin M.O., Geopolimernye stroitel'nye materialy na osnove promyshlennykh otkhodov (Geopolymer building materials based on industrial waste), Penza: PGUAS Publ., 2014, 128 p.

6. Rakhimov R.Z., Rakhimova N.R., Stoyanov O.V., Geopolymers (In Russ.), Vestnik Kazanskogo tekhnologicheskogo universiteta, 2014, V. 23, pp. 189-196.

7. Thomas R., Ye Hailong, Radlińska A., Peethamparan S., Alkali-activated slag cement concrete: A closer look at a sustainable alternative to Portland cement, Concrete International, 2016, V. 38, pp. 33–38.

8. Purdon A.O., The action of alkalis on blast-furnace slag, Journal of the Society of Chemical Industry, 1940, V. 59, no. 9, pp. 191–202.

9. Talling B., Effect of curing conditions on alkali-activated slags, Proceedings of 3rd International conference on the use of fly ash, silica fume, slag and natural pozzolans in concrete. ACI SP-114, 2, 1989, pp. 1485–1500.

10. Davidovits J., Davidovits R., Ferro-sialate geopolymers, Geopolymer Institute Library, 2020, Technical papers no. 27.

11. Suraneni P., Burris L., Shearer C., Hooton D., ASTM C618. Fly ash specification: Comparison with other specifications, shortcomings, and solutions, ACI Materials Journal, 2021, V. 118(1).

12. Na bloki i betony: predpriyatiya SGK za 2023 god realizovali 623 tysyachi tonn zoly-unosa (For blocks and concrete: enterprises of Siberian Generating Company LLC sold 623 thousand tons of fly ash in 2023), URL: https://sibgenco.online/news/element/na-bloki-i-betony-predpriyatiya-sgk-za-2023-god-realizovali-623...

13. Test results in DCL (Report No: 100064593, 100056083) in correspondence to EN standard: BS EN 1015-11:1999, Renca 3D geopolymer concrete, 2017

14. Salih M.A., Aldikheeli M.R., Shaalan k.A., Evaluation of factors influencing the compressive strength of Portland cement statistically, IOP Conference Series Materials Science and Engineering, 2020, V. 737, DOI: http://doi.org/10.1088/1757-899X/737/1/012059



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