The article discusses some issues of scientific justification for the exploration of fossil hydrogen in Russia and around the world. It emphasizes the general tendency of search orientation transition from surface features to features of medium and large depths. The level of knowledge about the conditions of hydrogen generation and localization in geological formations is demonstrated. The author's proposals for the development of the hydrogen prospecting paradigm are presented, within the framework of which a fundamentally important role is assigned to the conservation factor of native hydrogen generated during the geological history. Therefore, the authors suggest that large fields of hydrogen may be located below the dominant impermeable layer, within hydrodynamic levels beneath its bottom, with their characteristic regime of hydrodynamic stagnation. This ensures both lithological and hydrodynamic shielding for free hydrogen. The article also proposes possible approaches to classifying native hydrogen deposits for discussion, taking into account the dynamic nature of its formation and accumulation in different geological environments and assessing geological reserves for fields of various sizes. The development of the resource potential of native hydrogen is an important state task, which ensures the use of native hydrogen along with traditional (hydrocarbon) raw materials, which can be considered as an important stimulating factor for the development of local production in energy-deficient regions of the country.
References
1. Dmitrievskiy A.N., Mastepanov A.M., Bushuev V.V., Resource-innovative strategy of Russia’s economic development (In Russ.), Vestnik Rossiyskoy Akademii Nauk = Herald of the Russian Academy of Sciences, 2014, V. 84, no. 10, pp. 867–874, DOI: http://doi.org/10.1134/S1019331614050062
2. Polevanov V.I., Glaz’ev S.M., Prospecting for naturally occurring hydrogen in Russia: A basis of integration into a new technological paradigm (In Russ.), Nedropol’zovanie XXI vek, 2020, no. 4 (87), pp. 12–23.
3. Zgonnik V., The occurrence and geoscience of natural hydrogen: A comprehensive review, Earth-Science Reviews, 2020, V. 203,
DOI: http://doi.org/10.1016/j.earscirev.2020.103140
4. Aimikhe V.J., Eyankware O.E., Recent advances in white hydrogen exploration and production: A mini review, Journal of Energy Research and Reviews, 2023, V. 13, no. 4, pp. 64–79, DOI: http://doi.org/10.9734/jenrr/2023/v13i4272
5. Moretti I. et al., Hydrogen emanations in intracratonic areas: New guide lines for early exploration basin screening, Geosciences, 2021, V. 11, no. 3,
DOI: http://doi.org/10.3390/geosciences11030145
6. Fedonkin M.A., The role of hydrogen and metals in the formation and evolution of metabolic systems, Collected papers “Problems of the Origin and Evolution of the Biosphere”, 2008, pp. 417–438.
7. Larin V.N., Modern hydrogen degassing on the Russian platform (In Russ.), Byulleten’ Moskovskogo obshchestva ispytateley prirody. Otdel geologicheskiy, 2007,
V. 82, no. 5, C. 91.
8. Isaev V.P., Pastukhov N.P., Zony degazatsii prirodnogo vodoroda na vostoke Sibirskoy platformy (Natural hydrogen degassing zones in the east of the Siberian platform), Collected papers “Fundamental’nyy bazis innovatsionnykh tekhnologiy neftyanoy i gazovoy promyshlennosti” (Fundamental basis of innovative technologies in the oil and gas industry), Proceedings of All-Russian scientific conference with international participation dedicated to the 35th anniversary of the Institute of Oil and Gas Problems of the Russian Academy of Sciences, Moscow, 17-19 October 2022, pp. 337–339.
9. Levshunova S.P., Vodorod i ego biogeokhimicheskaya rol’ v obrazovanii uglevodorodnykh gazov v osadochnykh porodakh zemnoy kory (Hydrogen and its biogeochemical role in the formation of hydrocarbon gases in sedimentary rocks of the earth’s crust): thesis of doctor of geological and mineralogical science, Moscow, 1994.
10. Abukova L.A., Safarova E.A., Filippova D.S. et al., Hydrochemical and microbiological processes accompanying hybrid storage of hydrogen and methane in aquifers
(In Russ.), Aktual’nye problemy nefti i gaza, 2023, no. 3(42), pp. 221–234, DOI: http://doi.org/10.29222/ipng.2078-5712.2023-42.art14
11. Pastukhov N.P., Mikhaylov M.S., Prirodnyy vodorod Cibirskoy platformy: perspektivy, poiski i razvedka (Natural hydrogen of the Siberian platform: prospects, searches and exploration), Collected papers “GeoEvraziya-2022. Geologorazvedochnye tekhnologii: nauka i biznes” (GeoEurasia-2022. Geological exploration technologies: science and business), Proceedings of V International Geological and Geophysical Conference, Moscow, 30.03-01.04.2022, pp. 134–137.
12. Maiga O. et al., Characterization of the spontaneously recharging natural hydrogen reservoirs of Bourakebougou in Mali, Scientific Reports, 2023, V. 13, no. 1,
DOI: https://doi.org/10.1038/s41598-023-38977-y
13. Prinzhofer A., Cissé CS. T., Diallo A.B., Discovery of a large accumulation of natural hydrogen in Bourakebougou (Mali), International Journal of Hydrogen Energy, 2018, V. 43(42), pp. 19315–19326, DOI: http://doi.org/10.1016/j.ijhydene.2018.08.193
14. Rezaee R., Assessment of natural hydrogen systems in Western Australia, International Journal of Hydrogen Energy, 2021, V. 46, no. 66, pp. 33068–33077,
DOI: http://doi.org/10.1016/j.ijhydene.2021.07.149
15. Shinohara H., Volatile flux from subduction zone volcanoes: Insights from a detailed evaluation of the fluxes from volcanoes in Japan, Journal of Volcanology and Geothermal Research, 2013, V. 268, pp. 46–63, DOI: http://doi.org/10.1016/j.jvolgeores.2013.10.007
16. Qian-ning Tiana, Shu-qing Yaoa, Ming-juan Shaoa et al., Origin, discovery, exploration and development status and prospect of global natural hydrogen under the background of carbon neutrality, China Geology, 2022, V. 5, no. 4, pp. 722–733, DOI: http://doi.org/10.31035/cg2022046
17. Shakirov R.B., Chemical and isotopic characteristics of hydrocarbon gases from Mendeleev and Golovnin volcanoes, Kunashir Island (In Russ.), Geokhimiya = Geochemistry International, 2014, no. 3, pp. 267–267, DOI: http://doi.org/10.7868/S0016752514010063
18. Filippova D.S., Hydrogen in the geological environment: features of generation and accumulation (In Russ.), SOCAR Proceedings, 2023, Special Issue no. 2,
DOI: http://doi.org/10.5510/OGP2023SI200885
19. Bakirov A.A., Bakirov E.A., Melik-Pashaev V.S., Yudin G.T., Teoreticheskie osnovy i metody poiskov i razvedki skopleniy nefti i gaza (Theoretical foundations and methods of prospecting and exploration of oil and gas accumulations), Moscow: Vysshaya shkola Publ., 1976, 416 p.
20. Kalitskiy K.I., Geologiya nefti (Oil geology), Petrograd: Neftyanoe i slantsevoe khozyaystvo Publ., 1921, 224 p.
21. Gordienko V.V., On the circulation of hydrogen in the atmosphere and the Earth’s crust (In Russ.), Geofizicheskiy Zhurnal, 2021, V. 43(5), pp. 35-59,
DOI: https://doi.org/10.24028/gzh.v43i5.244051
22. Deeva T.A., Kamartdinov M.R., Kulagina T.E., Fizika plasta (Reservoir physics), Tomsk: Publ. of Tomsk Polytechnic University, 2010.
23. Molchanov V.I., Generatsiya vodoroda v litogeneze (Hydrogen generation in lithogenesis), Novosibirsk: Nauka Publ., 1981, 142 p.
24. Nenakhov V.M., Polevanov V.P., Zhabin A.V. et al., Prospects for the discovery of natural hydrogen in the Voronezh anteclise (In Russ.), Vestnik Voronezhskogo gosudarstvennogo universiteta. Seriya: Geologiya, 2022, no. 2, pp. 4–18, DOI: https://doi.org/10.17308/geology.2022.2/9275
25. Onezhskaya paleoproterozoyskaya struktura (geologiya, tektonika, glubinnoe stroenie i minerageniya) (Onega Paleoproterozoic structure (geology, tectonics, deep structure and minerageny)): edited by Glushanin L.V., Sharov N.V., Shchiptsov V.V., Petrozavodsk: Publ. of Karelian Scientific Center of the Russian Academy of Sciences, 2011, 431 p.