Import-substituting demulsifiers produced by the Science Development Production Company MACROMER in the name of V.S. Lebedev and the scientific basis of their development

UDK: 54-4:622.276
DOI: 10.24887/0028-2448-2024-4-103-106
Key words: oilfield chemicals, demulsifiers, oil-water emulsions, synergism, dielectric measurements
Authors: L.P. Semikhina (Tyumen Industrial University, RF, Tyumen; Science Development Production Company MACROMER in the name of V.S. Lebedev, RF, Vladimir), I.V. Kovaleva (Tyumen Industrial University, RF, Tyumen), E.A. Antipova (Science Development Production Company MACROMER in the name of V.S. Lebedev, RF, Vladimir), N.N. Evseeva (Science Development Production Company MACROMER in the name of V.S. Lebedev, RF, Vladimir), D.V. Semikhin (Tyumen State University, RF, Tyumen)

The article shows the possibility of developing of import-substituting highly effective demulsifiers for oil dehydration. This problem requires the solution of two tasks: the creation of industrial production of reagents with high demulsifying ability and different chemical nature and the development of a method for producing composite reagents from several chemical compounds with higher efficiency. The MACROMER company has been solving the first task for many years at its own pilot production, constantly expanding the range and increasing the efficiency of the produced reagents. To solve the second task, instead of the generally accepted world practice of empirical selection of the composition of reagents to assess the effectiveness of their impact on the technological process, this work shows the possibility of selecting reagents using a special dielectric method. It has been shown that the number of reagents with demulsifying ability produced by the MACROMER company is currently sufficient to create import-substituting demulsifiers. And using of the dielectric method to determine the composition of their optimal mixtures makes it possible to develop composite demulsifiers that are insensitive to the composition of oils and are even more effective compared to imported reagents.

References

1. Patent RU 2422494 C1, Demulsifier of resin kind for breaking stable emulsions of water-in-oil type, procedure for its production and device for it, Inventors: Antipova E.A., Potapochkina I.I., Lebedev V.S.

2. Semikhina L.P., Moskvina E.N., Kol’chevskaya I.V., The effect of synergism in surface-active reagents (In Russ.), Vestnik Tyumenskogo gosudarstvennogo universiteta. Ekologiya i prirodopol’zovanie, 2012, no. 5, pp. 85–91.

3. Patent RU 2301253 C1, Method of revealing synergetic effect in composite demulsifiers from low-frequency dielectric measurements, Inventors: Semikhina L.P., Semikhin D.V.

4. Semikhina L.P., Nizkochastotnaya diel’kometriya zhidkostey v slabykh vikhrevykh elektricheskikh polyakh (Low-frequency dielectric metering of liquids in weak vortex electric fields): thesis of doctor of physical and mathematical sciences, Tyumen’, 2001.

5. Patent RU 2413754 C1, Procedure for separation of water-oil emulsions with utilisation of nano de-emulsifiers, Inventor: Semikhina L.P.



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