Investigation of adsorption processes using atomic force microscopy on samples of terrigenous rocks from Zapadno-Salymskoye field

Authors: Yu.S. Zamula, L.A. Kovaleva, M.V. Mavletov (Bashkir State University, RF, Ufa), I.N. Koltsov (Salym Petroleum Development N.V., RF, Tyumen), I.Sh. Akhatov (Skolkovo Institute of Science and Technology, RF, Moscow)

Key words: adsorption, surfactant, atomic force microscopy.

The purpose of the experimental study is to estimate the thickness of the adsorbed surfactant layer on substrates of different mineral composition using AFM. Two series of experimental studies were set to study the adsorption of surfactant using AFM: 1) formation of surfactant aggregates due to adsorption from solution on a clean substrate, and 2) creating a residual oil layer on a substrate and washing it off using a surfactant. The substrates were selected: natural core and also mica and glass, as they are part of the real oil-bearing core. Both series used the same surfactant in two different concentrations (0.7 and 2.1%). For determination the thickness of the complex constructed adsorbed layer, filled with uniform and non-uniform layers of surfactant molecules a new technique was developed. The essence of this technique is a "scratching" the adsorption layer with subsequent extraction of sectional profile of obtained scan.
References
1. Markhasin I.L., Fiziko-khimicheskaya mekhanika neftyanogo plasta
(Physical and chemical mechanics of oil reservoir), Moscow: Nedra Publ.,
1977, 214 p.
2. Babalyan G.A., Levi B.I., Tumasyan A.B, Khalimov E.M., Razrabotka
neftyanykh mestorozhdeniy s primeneniem poverkhnostno-aktivnykh
veshchestv (Development of oil fields using surfactants), Moscow: Nedra
Publ., 1983, 216 p.
3. Babalyan G.L., Kravchenko I.I., Markhasin I.L., Rudakov G.V., Fizikokhimicheskie
osnovy primeneniya poverkhnostno-aktivnykh veshchestv pri
razrabotke neftyanykh plastov (Physical and chemical basics of using surfactants in the oil reservoirs development), Moscow: Gostoptekhizdat
Publ., 1962, 282 p.
4. Ebzeeva O.R., Zlobin A.A., Analysis of properties boundary layers oil after its water flooding (In Russ.), Vestnik Permskogo natsional'nogo issledovatel'skogo politekhnicheskogo universiteta. Geologiya. Neftegazovoe i gornoe delo, 2012, no. 2, pp. 87-94.
5. Mironov V.L., Osnovy skaniruyushchey zondovoy mikroskopii (Basics of the scanning probe microscopy), Moscow: Tekhnosfera Publ., 2005, 144 p.
6. Ono T., Li X., Miyashita H., Esashi M., Mass sensing of adsorbed molecules in sub-picogram sample with ultrathin silicon resonator, Rev. Sci. Instrum., 2003, V. 3, no. 74., pp. 1240–1243.
7. Liu J.F., Min G., Ducker W.A., AFM study of adsorption of cationic surfactants and cationic polyelectrolytes at the silica-water interface, Langmuir, 2001, V. 17, no. 16, pp. 4895–4903.
8. Seiedi O. et al., Atomic force microscopy (AFM) investigation on the surfactant wettability alteration mechanism of aged mica mineral surfaces, Energy Fuels, 2011, no. 25, pp. 183–188.
9. Shchukin E.D., Pertsov A.V., Amelina E.A., Kolloidnaya khimiya (Colloid
chemistry), Moscow: Vysshaya shkola Publ., 2004, 445 p.
10. Borodkin A.A., Evseeva M.Ya., Volokitin Ya.E. et al., Investigation of adsorption mechanisms in static conditions in order to reduce risks for the project of alkaline -surfactant - polymer flooding for conditions of West-Salymskoye field (In Russ.), Neftyanoe khozyaystvo = Oil Industry, 2013, no. 12, pp. 58–61.


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