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Investigating the structure and composition of heavy oil under thermal-catalytic treatment in presence of carbonaceous minerals

UDK: 552.578.2:536
DOI: 10.24887/0028-2448-2018-2-44-47
Key words: aquathermolysis, carbonaceous rock, calcite, dolomite, kaolin clay, pyrolusite, heavy oil
Authors: S.M. Petrov (Kazan (Volga Region) Federal University, RF, Kazan), D.A. Ibragimova (Kazan (Volga Region) Federal University, RF, Kazan), A.V. Vakhin (Kazan (Volga Region) Federal University, RF, Kazan), I.M. Zaidullin (Kazan National Research Technological University, RF, Kazan), G.R. Valieva (Kazan National Research Technological University, RF, Kazan), Z.R. Zakirova (Kazan National Research Technological University, RF, Kazan)

At present, great attention is paid to the study of the heavy crude oils and natural bitumens transformation occurring in the conditions of their extraction by steam-thermal methods acting on carbonate reservoir. The steam-assisted gravity drainage is a cost effective method for increasing the production of superviscous oil and providing access to reserves that were previously considered to be unrecoverable. Thermal methods of heavy oil recovery lead to various changes in the physical and chemical properties of the extracted crude oil. The same steam-thermal method can be highly efficient in certain reservoir conditions, while in others, its efficiency is zero or even negative. The knowledge of the peculiarities of the super-viscous oil structure and composition change after the steam-thermal method effect on the petroleum rock becomes necessary to sel ect the most effective steam-thermal technology for specific conditions of the reservoir.

The paper considers the influence of rock-forming minerals on the physical and chemical properties of heavy crude oil under steam-stimulation. Bio-degrade oil was performed in the presence of rock-forming additives among which are calcites, dolomite, kaolin clay and manganese oxide. In the experiments we varied temperature and pressure conditions. It was observed, that the temperature and pressure have a significant influence on the processes. The obtained samples after the steam-thermal stimulation characterizes by the lower structural and Newtonian flow viscosity, by great output of fuel and oil fractions than the heavy oil.

Resins converted into lighter components during the destruction. The steam stimulation destruction of high molecular compounds of oil occurs on the surface of the mineral additives with the large surface area of the catalyst capable of fiction. On the surface, additives partially structure a monomolecular surface layer with a decrease in entropy of the observed molecules. This leads to a shift in the equilibrium towards the unimolecular reaction of thermal decomposition of -C-C- bonds by radical chain mechanism. Thus, there are two competing mechanisms. On the one hand, the temperature increase raises processes of macromolecular compounds cracking, fr om the other hand growing temperature background in the absence of high pressure reduces the probability of adsorption on to the additive surface.

References

1. Kayukova G.P., Petrov S.M., Uspenskiy B.V., Svoystva tyazhelykh neftey i bitumov permskikh otlozheniy Tatarstana v prirodnykh i tekhnogennykh protsessakh (Properties of high-viscosity oil and bitumen of Permian deposits of Tatarstan in natural and technogenic processes), Moscow: GEOS Publ., 2015, 343 p.

2. Kayukova G.P., Gubaidullin A.T., Petrov S.M. et al., Changes of asphaltenes’ structural phase characteristics in the process of conversion of heavy oil in the hydrothermal catalytic system, Energy Fuels, 2016, V. 30, pp. 773–783.

3. Petrov S.M., Abdelsalam Ya.I., Vakhin A.V. et al., Study of the rheological properties of heat-treatment products of asphaltic oils in the presence of rock-forming minerals (In Russ.), Khimiya i tekhnologiya topliv i masel = Chemistry and Technology of Fuels and Oils, 2015, no. 1, pp. 79–82.

4. Vakhin A.V., Sitnov S.A., Mukhamatdinov I.I. et al., Aquathermolysis of high-viscosity oil in the presence of an oil-soluble iron-based catalyst (In Russ.), Khimiya i tekhnologiya topliv i masel = Chemistry and Technology of Fuels and Oils, 2017, no. 5, pp. 24–28.

5. Petrov S.M., Ibragimova D.A., Safiulina A.G. et al., Geothermal conversion of organic matter in the carbonaceous medium in the presence of homogeneous oxidation catalysts, Journal of Petroleum Science and Engineering, 2017, V. 159, pp. 497–505.

6. Galukhin A.V., Erokhin A.A., Osin Y.N., Nurgaliev D.K., Catalytic aquathermolysis of heavy oil with iron tris (acetylacetonate): Changes of heavy oil composition and in situ formation of magnetic nanoparticles, Energy Fuels, 2015, V. 29, pp. 4768–4773.

7. Kadiev Kh.M., Khadzhiev S.N., Kadieva M.Kh., Synthesis and use of polyfunctional catalyst nanoparticles for hydroconversion of natural bitumen (In Russ.), Neftekhimiya = Petroleum Chemistry, 2013, V. 53, no. 5, pp. 337.

8. Tumanyan B.P., Petrukhina N.N., Kayukova G.P. et al., Aquathermolysis of crude oils and natural bitumen: chemistry, catalysts and prospects for industrial implementation (In Russ.), Uspekhi khimii = Russian Chemical Reviews, 2015, V. 84(11), pp. 1145–1175.

9. Petrov S.M., Ibragimova D.A., Abdelsalam Ya.I.I. et al., Reforming of extra viscous oil in the presence of mineral additives of carbonate rock (In Russ.), Neftyanoe khozyaystvo = Oil Industry, 2016, no. 2, pp. 82–85.

10. Petrov S.M., Ibragimova D.A., Abdelsalam Ya.I.I., Kayukova G.P., Influence of rock-forming and catalytic additives on transformation of highly viscous heavy oil (In Russ.), Neftekhimiya = Petroleum Chemistry, 2016, V. 56, no. 1, pp. 24–29.

11. Sitnov S.A., Feoktistov D.A., Petrovnina M.S. et al., Structural changes of heavy oil in the composition of the sandstone in a catalytic and non-catalytic aquathermolysis, International Journal of Pharmacy and Technology, 2016, no. 8(3), pp. 15074–15080.

12. Maity S.K., Ancheyta J.; Marroquнn G., Catalytic aquathermolysis used for viscosity reduction of heavy crude oils: A review, Energy Fuels, 2010, V. 24, pp. 2809–2816.

13. Kudryashov S.I., Afanas'ev I.S., Petrashov O.V. et al., Catalytic heavy oil upgrading by steam injection with using of transition metals catalysts (In Russ.), Neftyanoe khozyaystvo = Oil Industry, 2017, no. 8, pp. 30–34.

At present, great attention is paid to the study of the heavy crude oils and natural bitumens transformation occurring in the conditions of their extraction by steam-thermal methods acting on carbonate reservoir. The steam-assisted gravity drainage is a cost effective method for increasing the production of superviscous oil and providing access to reserves that were previously considered to be unrecoverable. Thermal methods of heavy oil recovery lead to various changes in the physical and chemical properties of the extracted crude oil. The same steam-thermal method can be highly efficient in certain reservoir conditions, while in others, its efficiency is zero or even negative. The knowledge of the peculiarities of the super-viscous oil structure and composition change after the steam-thermal method effect on the petroleum rock becomes necessary to sel ect the most effective steam-thermal technology for specific conditions of the reservoir.

The paper considers the influence of rock-forming minerals on the physical and chemical properties of heavy crude oil under steam-stimulation. Bio-degrade oil was performed in the presence of rock-forming additives among which are calcites, dolomite, kaolin clay and manganese oxide. In the experiments we varied temperature and pressure conditions. It was observed, that the temperature and pressure have a significant influence on the processes. The obtained samples after the steam-thermal stimulation characterizes by the lower structural and Newtonian flow viscosity, by great output of fuel and oil fractions than the heavy oil.

Resins converted into lighter components during the destruction. The steam stimulation destruction of high molecular compounds of oil occurs on the surface of the mineral additives with the large surface area of the catalyst capable of fiction. On the surface, additives partially structure a monomolecular surface layer with a decrease in entropy of the observed molecules. This leads to a shift in the equilibrium towards the unimolecular reaction of thermal decomposition of -C-C- bonds by radical chain mechanism. Thus, there are two competing mechanisms. On the one hand, the temperature increase raises processes of macromolecular compounds cracking, fr om the other hand growing temperature background in the absence of high pressure reduces the probability of adsorption on to the additive surface.

References

1. Kayukova G.P., Petrov S.M., Uspenskiy B.V., Svoystva tyazhelykh neftey i bitumov permskikh otlozheniy Tatarstana v prirodnykh i tekhnogennykh protsessakh (Properties of high-viscosity oil and bitumen of Permian deposits of Tatarstan in natural and technogenic processes), Moscow: GEOS Publ., 2015, 343 p.

2. Kayukova G.P., Gubaidullin A.T., Petrov S.M. et al., Changes of asphaltenes’ structural phase characteristics in the process of conversion of heavy oil in the hydrothermal catalytic system, Energy Fuels, 2016, V. 30, pp. 773–783.

3. Petrov S.M., Abdelsalam Ya.I., Vakhin A.V. et al., Study of the rheological properties of heat-treatment products of asphaltic oils in the presence of rock-forming minerals (In Russ.), Khimiya i tekhnologiya topliv i masel = Chemistry and Technology of Fuels and Oils, 2015, no. 1, pp. 79–82.

4. Vakhin A.V., Sitnov S.A., Mukhamatdinov I.I. et al., Aquathermolysis of high-viscosity oil in the presence of an oil-soluble iron-based catalyst (In Russ.), Khimiya i tekhnologiya topliv i masel = Chemistry and Technology of Fuels and Oils, 2017, no. 5, pp. 24–28.

5. Petrov S.M., Ibragimova D.A., Safiulina A.G. et al., Geothermal conversion of organic matter in the carbonaceous medium in the presence of homogeneous oxidation catalysts, Journal of Petroleum Science and Engineering, 2017, V. 159, pp. 497–505.

6. Galukhin A.V., Erokhin A.A., Osin Y.N., Nurgaliev D.K., Catalytic aquathermolysis of heavy oil with iron tris (acetylacetonate): Changes of heavy oil composition and in situ formation of magnetic nanoparticles, Energy Fuels, 2015, V. 29, pp. 4768–4773.

7. Kadiev Kh.M., Khadzhiev S.N., Kadieva M.Kh., Synthesis and use of polyfunctional catalyst nanoparticles for hydroconversion of natural bitumen (In Russ.), Neftekhimiya = Petroleum Chemistry, 2013, V. 53, no. 5, pp. 337.

8. Tumanyan B.P., Petrukhina N.N., Kayukova G.P. et al., Aquathermolysis of crude oils and natural bitumen: chemistry, catalysts and prospects for industrial implementation (In Russ.), Uspekhi khimii = Russian Chemical Reviews, 2015, V. 84(11), pp. 1145–1175.

9. Petrov S.M., Ibragimova D.A., Abdelsalam Ya.I.I. et al., Reforming of extra viscous oil in the presence of mineral additives of carbonate rock (In Russ.), Neftyanoe khozyaystvo = Oil Industry, 2016, no. 2, pp. 82–85.

10. Petrov S.M., Ibragimova D.A., Abdelsalam Ya.I.I., Kayukova G.P., Influence of rock-forming and catalytic additives on transformation of highly viscous heavy oil (In Russ.), Neftekhimiya = Petroleum Chemistry, 2016, V. 56, no. 1, pp. 24–29.

11. Sitnov S.A., Feoktistov D.A., Petrovnina M.S. et al., Structural changes of heavy oil in the composition of the sandstone in a catalytic and non-catalytic aquathermolysis, International Journal of Pharmacy and Technology, 2016, no. 8(3), pp. 15074–15080.

12. Maity S.K., Ancheyta J.; Marroquнn G., Catalytic aquathermolysis used for viscosity reduction of heavy crude oils: A review, Energy Fuels, 2010, V. 24, pp. 2809–2816.

13. Kudryashov S.I., Afanas'ev I.S., Petrashov O.V. et al., Catalytic heavy oil upgrading by steam injection with using of transition metals catalysts (In Russ.), Neftyanoe khozyaystvo = Oil Industry, 2017, no. 8, pp. 30–34.



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